Thus, the solid lubricants additive would divide the resin structure, which induced stress concentration and the decrease of effective cross-sectional area bearing pressure. As a result, the impact strength of PA6/GF-15 composite decreased. With increasing the content selleck chem inhibitor of PTFE, the impact strength decreased first and then increased. The minimum value emerged when the additive amount was 10wt%. As for graphite and UHMWPE, the impact strength increased first and then decreased in the range of 5~20wt%. The maximum value appeared at 10wt% and 12wt%, respectively. With the addition of UHMWPE, the reduction of impact strength was much lower than filling with PTFE and graphite.Obviously, GF was an effective reinforcement for PA6 matrix in the present case.
Thus, the effects to be noted for the single solid lubricant on mechanical properties of PA6/GF-15 composite are as follows: (1) the effects of PTFE and UHMWPE fillers on hardness and tensile strength are fairly small; (2) graphite solid lubricant increases the tensile strength dramatically but makes the material soft; (3) all the three solid lubricants decrease the impact strength of PA6/GF-15 composite in different degree, which means that single solid lubricant makes the composite material brittle.Figure 2 illustrated the effects of three kinds of complex solid lubricants, PTFE/graphite, PTFE/UHMWPE, and graphite/UHMWPE, on mechanical properties of PA6/GF-15 composite. The total content of complex solid lubricants was fixed at 15wt%.
As is seen from the hardness in Figure 2(a), when PA6/GF-15 composite was filled without graphite, there was a slight change in hardness, which is the same trend as filling with single solid lubricant. If the softest graphite was added into composite, the hardness decreased.The variation of the tensile strength of PA6 and its composites with content ratio of complex solid lubricants is shown in Figure 2(b). When PTFE/graphite compound solid lubricant was added to PA6/GF-15 composite, there was approximately 32% increase in tensile strength as good as single graphite with the same amount value of 15wt%. This is mainly attributed to the presence of graphite particles, which can make the blend structure more homogeneous [13]. Consequently, the stretch-proof capacities of PA6 composites enhanced. However, when graphite and UHMWPE were selected as the compound solid lubricants, there was no obvious increase in tensile strength for composite.
This is believed to be caused by the difference of molecular weight between PTFE and UHMWPE, which can influence the compatibility between inorganic graphite material and organic solid lubricants. As for PTFE/UHMWPE compound solid lubricant, there was Dacomitinib practically no effect on the tensile strength of PA6/GF-15 composite as the same as single PTFE and UHMWPE solid lubricants.